Thermal Properties of Matter is Chapter 10 of NCERT Class 11 Physics (Part II) and part of Unit 7, Properties of Solids and Liquids, in both the NEET UG and JEE Main syllabus. These notes cover temperature scales, thermal expansion, specific heat, calorimetry, change of state, latent heat, conduction, convection, radiation and Newton’s law of cooling, with a PDF.
Thermal Properties of Matter Notes for NEET and JEE Main
Section-wise key points from NCERT Chapter 10, formula tables, high-yield facts and common mistakes for 2027 revision.
Thermal Properties of Matter at a Glance
| Item | Details |
|---|---|
| Syllabus unit | Unit 7: Properties of Solids and Liquids (same unit number in NEET UG and JEE Main) |
| Exams that cover it | NEET UG and JEE Main Paper 1 (B.E./B.Tech.) |
| NCERT textbook | Physics Part II, Class 11, Chapter 10 (rationalised book) |
| Other chapters in the unit | Mechanical Properties of Solids (Chapter 8), Mechanical Properties of Fluids (Chapter 9) |
| Syllabus topics | Heat, temperature, thermal expansion; specific heat capacity, calorimetry; change of state, latent heat; heat transfer: conduction, convection and radiation |
| Experimental skills (Unit 20) | Specific heat capacity of a given solid and liquid by the method of mixtures |
| Official chapter | NCERT Chapter 10 |
| Notes PDF | View PDF |
The topic list follows the NEET UG 2026 syllabus released by the National Medical Commission (NMC) on 22 December 2025 and the JEE Main 2026 syllabus published by the National Testing Agency (NTA). Both stay the reference until the 2027 syllabi are out. The full lists are on the NEET syllabus and JEE Main syllabus pages.
Temperature and Heat
Heat is energy that flows between a body and its surroundings because of a temperature difference; temperature is the measure of a body’s hotness.
- Heat flows from the body at higher temperature to the one at lower temperature until both reach the same temperature (thermal equilibrium).
- SI unit of heat: joule (J). SI unit of temperature: kelvin (K); °C is also commonly used.
- Any energy transfer that does not involve a temperature difference is not heat.
Measurement of Temperature and Temperature Scales
A thermometer uses a thermometric property that changes with temperature, such as the expansion of mercury or alcohol in a glass tube.
| Scale | Ice point | Steam point | Divisions between them |
|---|---|---|---|
| Celsius | 0 °C | 100 °C | 100 |
| Fahrenheit | 32 °F | 212 °F | 180 |
| Kelvin | 273.15 K | 373.15 K | 100 |
- Conversion: t<sub>F</sub> = (9/5)t<sub>C</sub> + 32, or (t<sub>F</sub> − 32)/180 = t<sub>C</sub>/100.
- Kelvin and Celsius have the same unit size: T = t<sub>C</sub> + 273.15.
- Liquid-in-glass thermometers using different liquids can disagree away from the fixed points; a constant-volume gas thermometer at low density gives the same reading whatever the gas.
- Absolute zero is −273.15 °C (0 K), the base of the Kelvin scale.
- The triple point of water, 273.16 K, is the preferred fixed point because it has a unique temperature.
Ideal-gas Equation and Absolute Temperature
Low-density gases obey PV = µRT, combining Boyle’s law (PV constant at fixed T) and Charles’ law (V/T constant at fixed P).
- µ is the number of moles and R = 8.31 J mol⁻¹ K⁻¹ is the universal gas constant.
- At constant volume, pressure varies linearly with temperature; extending the line to zero pressure gives −273.15 °C for every low-density gas.
Thermal Expansion
Most substances expand on heating; the fractional change in size per kelvin is the coefficient of expansion.
| Type | Definition | Relation |
|---|---|---|
| Linear | Δl/l = α<sub>l</sub>ΔT | – |
| Area | ΔA/A = α<sub>a</sub>ΔT | α<sub>a</sub> = 2α<sub>l</sub> |
| Volume | ΔV/V = α<sub>v</sub>ΔT | α<sub>v</sub> = 3α<sub>l</sub> |
- Metals expand more than glass: copper expands about five times more than glass for the same temperature rise.
- Alcohol (ethanol) has a larger α<sub>v</sub> than mercury.
- For an ideal gas at constant pressure, α<sub>v</sub> = 1/T; at 0 °C it is 3.7 × 10⁻³ K⁻¹, much larger than for solids and liquids.
- Anomalous expansion of water: it contracts on heating from 0 °C to 4 °C and has maximum density at 4 °C. Lakes therefore freeze from the top, and life below survives.
- Thermal stress: if a rod’s ends are fixed, stress = Yα<sub>l</sub>ΔT. NCERT example: a steel rail heated by 10 °C develops 2.4 × 10⁷ N m⁻².
Specific Heat Capacity and Calorimetry
The heat needed to raise a body’s temperature depends on its mass, the temperature change and the nature of the substance.
| Quantity | Definition | SI unit |
|---|---|---|
| Heat capacity | S = ΔQ/ΔT | J K⁻¹ |
| Specific heat capacity | s = (1/m)(ΔQ/ΔT) | J kg⁻¹ K⁻¹ |
| Molar specific heat capacity | C = (1/µ)(ΔQ/ΔT) | J mol⁻¹ K⁻¹ |
- For gases, C<sub>p</sub> (constant pressure) and C<sub>v</sub> (constant volume) are defined separately.
- Water has the highest specific heat capacity among the substances in NCERT’s table (4186 J kg⁻¹ K⁻¹), so it is used as a coolant in car radiators and in hot water bags, and sea breezes have a cooling effect.
- Calorimetry: in an isolated system, heat lost by the hotter part equals heat gained by the colder part.
- A calorimeter is a metal vessel and stirrer of the same material (copper or aluminium) inside a wooden jacket packed with an insulator such as glass wool.
Change of State and Latent Heat
During a change of state, added heat changes the state, not the temperature: Q = mL.
| Change | Name | Latent heat of water at 1 atm |
|---|---|---|
| Solid to liquid | Melting (fusion) | L<sub>f</sub> = 3.33 × 10⁵ J kg⁻¹ at 0 °C |
| Liquid to vapour | Vaporisation (boiling) | L<sub>v</sub> = 22.6 × 10⁵ J kg⁻¹ at 100 °C |
| Solid directly to vapour | Sublimation | Examples: dry ice (solid CO₂), iodine |
- Steam at 100 °C carries 22.6 × 10⁵ J kg⁻¹ more heat than water at 100 °C, so steam burns are more serious.
- Regelation: ice melts under pressure and refreezes when the pressure is removed (a weighted wire passes through an ice slab); skating works because pressure forms water under the skates.
- Boiling point falls with lower pressure (cooking is hard on hills) and rises with higher pressure (a pressure cooker cooks faster). The boiling point at 1 atm is the normal boiling point.
- The triple point is where solid, liquid and vapour coexist; for water it is 273.16 K.
- L depends on pressure; values are usually quoted at standard atmospheric pressure.
Heat Transfer: Conduction, Convection and Radiation
Heat moves by three modes; conduction and convection need a medium, radiation does not.
| Mode | How heat moves | Medium needed | Example |
|---|---|---|---|
| Conduction | Molecular collisions between neighbouring parts, no flow of matter | Yes (mainly solids) | Copper-bottomed cooking pots |
| Convection | Bulk motion of the fluid | Yes (fluids only) | Sea breeze, trade winds, car cooling system |
| Radiation | Electromagnetic waves at 3 × 10⁸ m s⁻¹ | No | Heat from the Sun reaching the earth |
Conduction
- Rate of heat flow through a bar: H = KA(T<sub>C</sub> − T<sub>D</sub>)/L, where K is the thermal conductivity (SI unit W m⁻¹ K⁻¹).
- Metals are good conductors (copper 385 W m⁻¹ K⁻¹); air is a poor conductor (0.024 W m⁻¹ K⁻¹).
- Two bars of equal length and area in series: junction temperature T₀ = (K₁T₁ + K₂T₂)/(K₁ + K₂) and equivalent conductivity K′ = 2K₁K₂/(K₁ + K₂).
Convection
- Natural convection depends on gravity and buoyancy; forced convection uses a pump, as in home heating, the human circulatory system and car engine cooling.
- By day the land heats faster than the sea, giving a sea breeze; at night the cycle reverses.
- Trade winds blow from the north-east towards the equator because of unequal solar heating modified by the earth’s rotation.
Radiation
- Black bodies absorb and emit radiation better than light-coloured bodies: white clothes in summer, dark clothes in winter, blackened bottoms of cooking pots.
- A thermos (Dewar) flask has double glass walls coated with silver, with vacuum between them to cut conduction and convection.
Blackbody Radiation: Wien’s and Stefan-Boltzmann Laws
Thermal radiation has a continuous spectrum, and its peak shifts to shorter wavelengths as temperature rises.
- Wien’s displacement law: λ<sub>m</sub>T = constant = 2.9 × 10⁻³ m K.
- Heated iron glows dull red, then reddish yellow, then white hot.
- NCERT estimates: the moon (λ<sub>m</sub> about 14 µm) at 200 K; the Sun’s surface (λ<sub>m</sub> = 4753 Å) at 6060 K.
- Blackbody curves are universal: they depend only on temperature, not on the size, shape or material of the body.
- Stefan-Boltzmann law for a perfect radiator: H = AσT⁴, with σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴.
- For a body of emissivity e: H = AeσT⁴; net loss to surroundings at T<sub>s</sub>: H = eσA(T⁴ − T<sub>s</sub>⁴).
- e = 1 for a perfect radiator; lamp black comes close, and a tungsten lamp has e of about 0.4.
Newton’s Law of Cooling
The rate at which a body loses heat is proportional to the difference between its temperature and that of its surroundings, for small temperature differences.
- −dQ/dt = k(T₂ − T₁), where T₂ is the body’s temperature, T₁ the surroundings’ and k depends on the area and nature of the surface.
- With dQ = ms dT₂: dT₂/dt = −K(T₂ − T₁), K = k/ms, giving T₂ = T₁ + C′e<sup>−Kt</sup>.
- The rate of cooling is highest at first and falls as the body approaches room temperature.
- It applies to a radiator warming a room, heat loss through a wall, or a cup of tea cooling on a table.
Most-asked Facts for NEET and JEE Main: Thermal Properties of Matter
Revise these one-line facts from the NCERT chapter just before the exam.
- t<sub>F</sub> = (9/5)t<sub>C</sub> + 32; T = t<sub>C</sub> + 273.15.
- Triple point of water: 273.16 K.
- α<sub>a</sub> = 2α<sub>l</sub>; α<sub>v</sub> = 3α<sub>l</sub>; for an ideal gas α<sub>v</sub> = 1/T.
- Water has maximum density at 4 °C.
- Thermal stress = Yα<sub>l</sub>ΔT.
- Specific heat of water = 4186 J kg⁻¹ K⁻¹.
- L<sub>f</sub> (ice) = 3.33 × 10⁵ J kg⁻¹; L<sub>v</sub> (water) = 22.6 × 10⁵ J kg⁻¹.
- Boiling point rises with pressure.
- H = KAΔT/L for conduction.
- Convection happens only in fluids; radiation needs no medium.
- λ<sub>m</sub>T = 2.9 × 10⁻³ m K (Wien).
- H = AeσT⁴, σ = 5.67 × 10⁻⁸ W m⁻² K⁻⁴ (Stefan-Boltzmann).
- Newton’s law of cooling holds for small temperature differences.
Common Mistakes to Avoid
Watch for these mix-ups when you answer questions on this chapter.
- Treating heat and temperature as the same thing. Heat is energy in transit; temperature is a measure of hotness.
- Writing α<sub>v</sub> = 2α<sub>l</sub>. Volume expansion is 3α<sub>l</sub>; area expansion is 2α<sub>l</sub>.
- Saying water is densest at 0 °C. It is densest at 4 °C.
- Raising the temperature during a phase change in calculations. Temperature stays constant while latent heat is absorbed or released.
- Using Celsius temperatures in the Stefan-Boltzmann law. T must be in kelvin.
- Applying Newton’s law of cooling to large temperature differences. It is valid only for small differences.
- Calling the cooling of a hot bar under running water convection. NCERT notes the bar loses heat by conduction to the water.
Thermal Properties of Matter Notes PDF and Related Pages
Download the AglaSem Class 11 Physics notes on Properties of Matter (key notes and important questions with answers) free: View PDF. This PDF covers the whole Properties of Solids and Liquids unit; its theory pages on heat cover thermal radiation (Stefan’s and Wien’s laws), and its question bank includes thermal expansion, specific heat, latent heat and conduction.
- All chapters: Physics notes for NEET and JEE Main
- Full topic list: NEET syllabus and JEE Main syllabus
- Practice: NEET question papers and JEE Main question papers
- Source text: NCERT Chapter 10 (NCERT, Class 11 Physics Part II)
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- Units and Measurement
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- Systems of Particles and Rotational Motion
- Gravitation
- Mechanical Properties of Solids
- Mechanical Properties of Fluids
- Thermodynamics
- Kinetic Theory of Gases
- Oscillations
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- Thermal Properties of Matter
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